Get all the updates for this publication
Articles
Formation of a room temperature stable Fev(o) complex: Reactivity toward unactivated c-h bondsPublished in American Chemical Society
2014
DOI: 10.1021/ja412537m
PMID: 24387595
Volume: 136
Issue: 27
Pages: 9524 - 9527
An FeV(O) complex has been synthesized from equimolar solutions of (Et4N)2[FeIII(Cl)(biuret-amide)] and mCPBA in CH3CN at room temperature. The FeV(O) complex has been characterized by UV-vis, EPR, Mössbauer, and HRMS and shown to be capable of oxidizing a series of alkanes having C-H bond dissociation energies ranging from 99.3 kcal mol-1 (cyclohexane) to 84.5 kcal mol-1 (cumene). Linearity in the Bell-Evans-Polayni graph and the finding of a large kinetic isotope effect suggest that hydrogen abstraction is engaged the rate-determining step. © 2014 American Chemical Society.
Preprint Version
Content may be subject to copyright.This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Jou... ...This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Journal of the American Chemical Society, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/ja412537m
About the journal
Published in American Chemical Society
Open Access
Impact factor
N/AAuthors (1)
Basab Bijayi Dhar- Phosphorous-doped graphitic material as a solid acid catalyst for microwave-assisted synthesis of β-ketoenamines and baeyer-villiger oxidation
- Selective U(VI) removal using phosphorous-doped graphitic carbon
- Solid Supported Nano Structured Cu-Catalyst for Solvent/Ligand Free C2 Amination of Azoles
- Aerobic oxidative amidation of alkynes using titanium oxide encapsulated cuprous iodide nanoparticles (CuI@TiO2)
