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Embedding a Ruthenium-Based Structural Mimic of the [Fe]-Hydrogenase Cofactor into PapainPublished in American Chemical Society
2018
PMID: 30198260
Volume: 57
Issue: 19
Pages: 12206 - 12212
We describe the synthesis of the ruthenacyclic carbamoyl complexes [Ru(2-NHC(O)C5H3NMe)(CO)2(o,o-Me2-C6H3S)(L)] (L = H2O or MeCN), which have a labile water or acetonitrile ligand at their sixth coordination sites. Steric bulk around the ruthenium center is essential in preventing isomerization and dimerization, and embedding within papain can be achieved via coordination of its sole free cysteine residue. The observed chemistry parallels that of the natural [Fe]-hydrogenase. Copyright © 2018 American Chemical Society.
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Content may be subject to copyright.This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Ino... ...This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.8b01835
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