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Very strong trans effect in ruthenacyclic carbamoyl complexes leads to ligand redistribution in phosphine derivativesPublished in Elsevier B.V.
2019
Volume: 887
Pages: 5 - 11
The ruthenacyclic carbamoyl complexes [Ru (2-NHC(O)C5H4N) (CO)2(X) (NCMe)] (X = Cl, Br) (1) and [Ru (2-NHC(O)C5H4N) (CO)2 (2-S-Py)] (2) undergo substitution reactions with organophosphines to afford derivatives which are prone to a redistribution of the phosphine ligand. We have studied these redistribution reactions experimentally and computationally, and proposed an essentially common reaction pathway. The results suggest that the carbamoyl ligand exerts a very strong trans effect. © 2019 Elsevier B.V.
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Published in Elsevier B.V.
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