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Unexpected conversion of alkyl azides to alkyl iodides and of aryl azides to N-tert-butyl anilines
Julien Maury, Laurence Feray, Mich{\`{e}}le Bertrand P., , Philippe Renaud
Published in
Volume: 68
Issue: 47
Pages: 9606 - 9611
In the presence of tert-butyl iodide, alkyl azides are converted into the corresponding iodides at room temperature, whereas, N-t-Bu anilines are obtained from aryl azides under the same experimental conditions. A mechanism is proposed to explain this unusual reactivity. {\textcopyright} 2012 Elsevier Ltd. All rights reserved.
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