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The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P4(NtBu)6: Enabled by MechanochemistryPublished in Wiley-VCH Verlag
2016
Volume: 55
Issue: 41
Pages: 12736 - 12740
All reported attempts to synthesize the tert-butyl-substituted adamantoid phosph(III)azane P4(NtBu)6have failed, leading to the classification of this molecule as inaccessible and a literature example of steric control in chemistry of phosphorus-nitrogen compounds. We now demonstrate that this structure is readily accessible by a solvent-free mechanochemical milling approach, highlighting the importance of mechanochemical reaction environments in evaluating chemical reactivity. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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Content may be subject to copyright.This is the peer reviewed version of the following article: [The First Synthesis of the Sterically Encumbered Adamantoid... ...This is the peer reviewed version of the following article: [The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P4(NtBu)6: Enabled by Mechanochemistry. Angewandte Chemie International Edition 55, 41 p12736-12740 (2016)], which has been published in final form at https://doi.org/10.1002/anie.201605936. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions: https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html#3.
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Published in Wiley-VCH Verlag
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