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The evolution of terminal allylphosphinidene pentacarbonyltungsten complex
F. Ho, Y. Li, , F. Mathey
Published in Taylor and Francis Ltd.
Volume: 189
Pages: 908 - 913
DFT computations suggest that terminal allylphosphinidene pentacarbonyltungsten complex 1 can evolve either by intramolecular P + CC cycloaddition or by [1,2] H C to P shift to give 2 or 6. Upon thermolysis of the 7-allyl-7-phosphanorbornadiene precursor, the transient complex 1 gives two diastereomeric dimers 4a,b deriving from a head-to-tail P + CC intermolecular cycloaddition and another dimer 5 deriving from the [4 + 1] cycloaddition of 1 with 6, followed by an intramolecular hydrophosphination. © 2014 Taylor & Francis Group, LLC.
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Published in Taylor and Francis Ltd.
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