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Synthesis, characterization and crystal structure of a diketone based Cu(II) complex and its catalytic activity for the synthesis of 1,2,3-triazoles
S. Layek, S. Kumari, Anuradha, B. Agrahari, , D.D. Pathak
Published in Elsevier S.A.
2016
Volume: 453
   
Pages: 735 - 741
Abstract
The synthesis and characterization of complex [Cu(dppo)2] (dppo = 1,3-diphenylpropane-1,3-dione) is reported. The complex has been fully characterized by FT-IR, UV–vis, elemental analysis and Cyclic Voltammetry. The paramagnetic nature of the complex was confirmed by magnetic measurement and the square planar geometry was ascertained by single crystal X-ray determination. The complex has been found to be a good homogeneous catalyst for the synthesis of 1,2,3-triazole derivatives via one-pot reaction of arylboronic acids, sodium azide and alkynes in DMF. © 2016 Elsevier B.V.
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Published in Elsevier S.A.
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