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Synthesis and thermal behaviour of thiophene-based oxazine-ring substituted benzoxazine monomers & polymers
S. Mukherjee,
Published in Royal Society of Chemistry
PMID: 35170626
Volume: 58
Issue: 22
Pages: 3609 - 3612
The latest fourth-generation oxazine-ring substituted thiophene-based benzoxazine monomers and polymers with variation in the degree of phenyl substitution (with and without) in the oxazine-ring were synthesized and characterized. Thiophene-based di-substituted benzoxazine undergoes ring-opening polymerization at a low temperature with a minimal mass loss during polymerization as supported by molecular geometry-guided intramolecular interactions. This class of monomers provides ample opportunities to design at the molecular level high-performance polybenzoxazines with promising smart applications. © 2022 The Royal Society of Chemistry.
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Published in Royal Society of Chemistry
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