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Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
E. Kumaran, K.T.S. How, , Y. Li, W.K. Leong
Published in
Volume: 32
Issue: 15
Pages: 4149 - 4152
The reaction of a terminal alkyne (RCCH) and 2-aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ =C(CH2R)NHC5NH 3R′] via a hydroamination and a ligand substitution. The reaction pathway has been examined through computational studies. © 2013 American Chemical Society.
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