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Synthesis and Hydrolytic Studies on the Air-Stable [(4-CN-PhO)(E)P(μ-NtBu)]2 (E = O, S, and Se) Cyclodiphosphazanes
Y.X. Shi, R.Z. Liang, K.A. Martin, N. Weston, S. Gonzalez-Calera, , Y. Li, Y. Lu, A.J.M. Ribeiro, M.J. RamosShow More
Published in American Chemical Society
Volume: 54
Issue: 13
Pages: 6423 - 6432
Reaction of 4-CN-PhOH with [ClP(μ-NtBu)]2 (1) (2:1 ratio) in the presence of Et3N produced the functionalized cyclodiphosph(III/III)azane [(4-CN-PhO)P(μ-NtBu)]2 (2). Oxidation of 2 produced cyclodiphosph(V/V)azanes [(4-CN-PhO)(E)P(μ-NtBu)]2 [E = O (3), S (4), and Se (5)]. This is the first example of a series of cyclodiphosph(V/V)azane derivatives obtained from a single cyclophosph(III/III)azane precursor where all the accessible chalcogen oxidized products are air-stable over prolonged periods of time. (Figure Presented). © 2015 American Chemical Society.
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