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Study on some metal(III) complexes with pyrazine-2-carboxylic and pyridine-2-carboxylic acids
GS Sanyal, , PK Nath, S Das, RJ Butcher
Published in
2001
Volume: 78
   
Issue: 9
Pages: 444 - 447
Abstract
Complexes of Cr-III, Co-III, Al-III and Bi-III with pyrazine-2-carboxylic acid along with some of their picolinates have been synthesized. The ligands are bidentate coordinating through a heterocyclic ring nitrogen and a carboxyl oxygen. A single crystal X-ray analysis on Cr(Pz-2-COO)(3) reveals the structure as highly distorted octahedral, Cr sitting at the center and surrounded by the bidentate ligand.
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