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Structural Mimics of the [Fe]-Hydrogenase: A Complete Set for Group VIII Metals
C.K. Barik, , Y. Li, W.K. Leong
Published in American Chemical Society
PMID: 29799728
Volume: 57
Issue: 12
Pages: 7113 - 7120
A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand. © 2018 American Chemical Society.
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Published in American Chemical Society
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