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Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal-organic framework
Xiao-Jun Wang, Pei-Zhou Li, Lei Liu, Quan Zhang, Parijat Borah, Jinye Wong Daniel, Xiu Chan Xiang, , Yongxin Li, Yanli Zhao
Published in
Volume: 48
Issue: 83
Pages: 10286 - 10288
Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N-2 and CH4.
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