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Serendipitous Observation of AlI Insertion into a C-O Bond in L2PhB (L=Oxazol-2-ylidene)
L. Kong, , Y. Li, R. Kinjo
Published in Wiley-VCH Verlag
2016
Volume: 22
   
Issue: 6
Pages: 1922 - 1925
Abstract
Oxidative addition of the C-O bond in L2PhB: (L=oxazol-2-ylidene) to an AlI center induced ring expansion of an oxazol-2-ylidene ring, affording a unique organoboron species formally involving either an Al, N, O mixed heterocyclic carbene or anionic (amino)(boryl)carbene fragment. Ring expansion of an oxazol-2-ylidene in L2PhB (L=oxazol-2-ylidene) through cleavage of the C-O bond by AlI resulted in the formation of a unique organoboron species formally involving either an Al, N, O mixed heterocyclic carbene or an anionic (amino)(boryl)carbene fragment. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Published in Wiley-VCH Verlag
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