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Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride
J.-Y. Guo, Y. Li, , C.-W. So
Published in
Volume: 31
Issue: 10
Pages: 3888 - 3893
The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh 2=NSiMe 3)(PPh 2=S)CSn:] 2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pr i 2C 6H 3), and [RhCl(cod)] 2 in THF afforded [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ad)}Sn:] (2), [(PPh 2=NSiMe 3)(PPh 2=S)C{C(O)N(Ar)}Sn +:] (3), and [(PPh 2=NSiMe 3)(PPh 2=S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography. © 2012 American Chemical Society.
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