Get all the updates for this publication
Articles
Reactivity of a tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex toward gallium, germanium, and zinc compoundsPublished in
2013
DOI: 10.1021/om400141j
Volume: 32
Issue: 9
Pages: 2643 - 2648
The reactivity of the tin(II) 1,3-benzodi(thiophosphinoyl)methanediide complex [{μ-1,3-C6H4(PhPS)2C}Sn]2 (1) toward GaCl3, GeCl4, and ZnEt2 is described. The reaction of 1 with 1.7 equiv of GeCl4 in CH 2Cl2 at room temperature afforded [1,3-C6H 4(PhPS)2C(GeCl3)SnCl]2 (2). Treatment of 1 with 1.7 equiv of ZnEt2 in refluxing toluene afforded [{1,3-C6H4(PhPS)2CSnEt2}(μ-ZnS)] 2 (3). Compound 1 also reacted with 1.7 equiv of GaCl3 in CH2Cl2 to afford [1,3-C6H4(PhPS) 2C(Sn)(GaCl3)] (4). Compounds 2-4 have been characterized by NMR spectroscopy and X-ray crystallography. © 2013 American Chemical Society.
Content may be subject to copyright.
About the journal
Published in
Open Access
Impact factor
N/AAuthors (1)
Rakesh Ganguly- Size-control in the synthesis of oxo-bridged phosphazane macrocycles via a modular addition approach
- Synthesis, structure, luminescent properties and catecholase activity of Zn(II) complex with N, O chelating agent
- Tetranuclear copper(ii) cubane complexes derived from self-assembled 1,3-dimethyl-5-(o-phenolate-azo)-6-aminouracil: structures, non-covalent interactions and magnetic property
- Investigating the solid-state assembly of pharmaceutically-relevant: N, N -dimethyl- O -thiocarbamates in the absence of labile hydrogen bonds
