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Oxidative addition of water and methanol to a dicationic trivalent phosphorus centre
M.Q.Y. Tay, Y. Lu, , D. Vidovic̈
Published in Wiley-VCH Verlag
2014
Volume: 20
   
Issue: 22
Pages: 6628 - 6631
Abstract
Our recently synthesised phosphorus dication is observed to activate water (and methanol) under reactions conditions atypical for other systems containing a non-metal centre. This particular activation described as oxidative addition is quite rare and has been reserved exclusively for a couple of metal-based compounds. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Published in Wiley-VCH Verlag
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