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Isolation of a cyclic (alkyl)(amino)germylene
L. Wang, Y.S. Lim, Y. Li, , R. Kinjo
Published in MDPI AG
PMID: 27483223
Volume: 21
Issue: 8
A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. © 2016 by the authors; licensee MDPI, Basel, Switzerland.
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Published in MDPI AG
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