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Isolation and Reactivity of 1,4,2-Diazaborole
B. Su, Y. Li, , J. Lim, R. Kinjo
Published in American Chemical Society
Volume: 137
Issue: 35
Pages: 11274 - 11277
An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated. © 2015 American Chemical Society.
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Published in American Chemical Society
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