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Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes
M.Q.Y. Tay, B. Murugesapandian, Y. Lu, , K. Rei, D. Vidović
Published in Royal Society of Chemistry
Volume: 43
Issue: 41
Pages: 15313 - 15316
The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain. This journal is © the Partner Organisations 2014.
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Published in Royal Society of Chemistry
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