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Activation of a 1-chlorophosphirane complex by aluminum trichloride: Generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
F. Ho, , F. Mathey
Published in Wiley-VCH Verlag
Volume: 2014
Issue: 28
Pages: 4726 - 4729
Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP-W(CO)5], which is trapped by tolan, trans-stilbene, and water. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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