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A Well-Defined Aluminum-Based Lewis Acid as an Effective Catalyst for Diels-Alder Transformations
Z. Liu, J.H.Q. Lee, , D. Vidovic
Published in Wiley-VCH Verlag
Volume: 21
Issue: 32
Pages: 11344 - 11348
A catalytically active aluminum-based system for Diels-Alder transformations is reported. The system was generated by mixing a β-diketiminate-stabilized aluminum bistriflate compound with Na[BArCl4] (ArCl=3,5-Cl2C6H3). Solid-state analysis of the catalytic system reveals a unique structure incorporating a two-dimensional coordination polymer. According to the experimental results obtained from several Diels-Alder transformations, the aluminum-based system appears to be a more practical and more robust alternative to the recently reported compounds based on carbon and silicon cations. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Published in Wiley-VCH Verlag
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