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A radical procedure for the anti-markovnikov hydroazidation of alkenes
, Andreas K{\"{o}}nig, Florian Montermini, Philippe Renaud
Published in
Volume: 133
Issue: 35
Pages: 13890 - 13893
A one-pot procedure for the efficient hydroazidation of alkenes involving hydroboration with catecholborane followed by reaction with benzenesulfonyl azide in the presence of a radical initiator is described. The regioselectivity is controlled by the hydroboration step and corresponds in most cases to an anti-Markovnikov regioselectivity. This procedure is applicable to a wide range of alkenes and gives excellent results with 1,2-disubstituted and trisubstituted alkenes. {\textcopyright} 2011 American Chemical Society.
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