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A carbone-stabilized two-coordinate phosphorus(III)-centered dication
M.Q.Y. Tay, Y. Lu, , D. Vidovic̈
Published in
Volume: 52
Issue: 11
Pages: 3132 - 3135
A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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