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1,5,9-Triaza-2,6,10-triphenylboracoronene: BN-embedded analogue of coronene
G. Li, W.-W. Xiong, P.-Y. Gu, J. Cao, J. Zhu, , Y. Li, A.C. Grimsdale, Q. Zhang
Published in American Chemical Society
Volume: 17
Issue: 3
Pages: 560 - 563
A novel BN-fused coronene derivative 1,5,9-triaza-2,6,10-triphenylboracoronene (1) has been successfully synthesized in one step from 2,3,6,7,9,10-hexamethoxy-1,5,9-triamino-triphenylene. Compound 1 has been investigated using photophysical, electrochemical, and molecular simulation methods. Interestingly, three phenyl groups at B centers in compound 1 can be replaced by hydroxyl units stepwise through hydroxylation in wet organic solvents, leading to changes in the packing and physical properties. © 2015 American Chemical Society.
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Published in American Chemical Society
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